Production and characterization of Imperata cylindrica paper using potassium hydroxide as pulping agent

##plugins.themes.bootstrap3.article.main##

ZULIANA MADUNG
SABRINA SOLOI
MOHD HAFIZ ABD MAJID
MOHD SANI SARJADI

Abstract

Abstract. Madung Z, Soloi S, Majid MHA, Sarjadi MS. 2022. Production and characterization of Imperata cylindrica paper using potassium hydroxide as pulping agent. Biodiversitas 23: 1490-1494. Non-woody plants have become an alternative fiber in paper production as woods, the primary sources of papers have become limited due to increasing demand of paper year by year. Imperata cylindrica or cogon grass as the source of fiber for the pulp and paper industry in replacing the wood fiber because it has high cellulose and low lignin content.  In this study, cogon grasses were treated with various concentrations of potassium hydroxide, KOH (5%, 8%, 10% and 12%). The effects of alkali treatment on the properties of the papers were investigated in the present study. Scanning Electron Microscope (SEM) image of the paper sheet indicates that the amount of cellulose fiber and other materials were lessening toward a higher concentration of KOH treatment. This explained that most of the lignin was entirely removed and some cellulose probably degraded at higher KOH concentrations. Fourier Transform Infa-Red (FTIR) analysis showed that the peaks at range 1650 cm-1-1630 cm-1 attributed to the presence of v(C=C) aromatic ring of lignin disappeared at 10% and 12% of KOH. The mechanical strength of the papers decreased with an increasing concentration of KOH, while 5% of KOH produced the highest value of tensile strength.

##plugins.themes.bootstrap3.article.details##

References
Abd El-Sayed, E.S., El-Sakhawy, M. and El-Sakhawy, M.A.-M. 2020. Non-wood fibers as raw material for pulp and paper industry. Nordic Pulp & Paper Research Journal 35(2) :215–230.
Bochek, A. 2003. Effect of Hydrogen Bonding on Cellulose Solubility in Aqueous and Nonaqueous Solvents. Russian Journal of Applied Chemistry 76 :1711–1719.
Brännvall, E. 2017. The limits of delignification in kraft cooking. BioResources 12(1): 2081–2107.
Chen, H. and Wang, L. 2017. Chapter 3 - Pretreatment Strategies for Biochemical Conversion of Biomass. In Chen, H. and Wang, L. (eds) Technologies for Biochemical Conversion of Biomass. Oxford: Academic Press.
Doherty, B. and Rainey, T. 2006. Bagasse Fractionation by The Soda Process. In Hoghart D M (Ed.) Proceeding of The Australian Society of Sugar Cane Technologist 2006. [Australia].
Höller, M. Lunze A, Wever C, Deutschle A, Stücker A. 2021. Meadow hay, Sida hermaphrodita (L.) Rusby and Silphium perfoliatum L. as potential non-wood raw materials for the pulp and paper industry. Industrial Crops and Products 67 :113548.
Hospodarova, V., Singovszka, E. and Stevulova, N. 2018. Characterization of Cellulosic Fibers by FTIR Spectroscopy for Their Further Implementation to Building Materials. American Journal of Analytical Chemistry 09(06) : 303–310.
Ibrahim, M.N.M., Yusof, N.N.M. and Hashim, A. 2007. Comparison Studies on Soda Lignin and Soda-Anthraquinone Lignin. The Malaysian Journal of Analytical Sciences 11(1) : 206–212.
Izzuddin Zaman, Al Emran Ismail, and Muhamad Khairudin Awang. 2009. Influence of Fiber Volume Fraction on the Tensile Properties and Dynamic Characteristics of Coconut Fiber Reinforced Composite. Journal of Science and Technology, 1(1) : 55-78
Judt, M. 1993. Non-wood plant fibres, will there be a come-back in paper-making?. Industrial Crops and Products 2(1) :51–57.
Kamoga, O.L.M., Byaruhanga, J.K. and Kirabira, J.B. 2013. A Review on Pulp Manufacture from Non Wood Plant Materials. International Journal of Chemical Engineering and Applications : 144–148.
Karlsson, H.K. 2010. Strength Properties of Paper produced from Softwood Kraft Pulp?: Pulp Mixture, Reinforcement and Sheet Stratification. [Thesis]. Karlstad University. [Sweeden].
Kassim, A.S.M. Aripin A.M, Ishak N, Zainulabidin M.H. 2016. Potential of cogon grass (Imperata cylindrica) as an alternative fibre in paper-based industry. ARPN Journal of Engineering and Applied Sciences 11(4) : 2681–2686.
Laftah, W.A. and Abdul Rahaman, W.A.W. 2015. Chemical pulping of waste pineapple leaves fiber for kraft paper production. Journal of Materials Research and Technology 4(3) : 254–261.
Liu, Y., Hu, T., Wu Z., Zeng G., Huang D., Shen Y., He X., Lai M., He Y. 2014 Study on biodegradation process of lignin by FTIR and DSC. Environmental science and pollution research international 21(24) : 14004–14013.
Lupoi, J.S., Singh S., Simmons B.A., Henry R.T. 2014. Assessment of Lignocellulosic Biomass Using Analytical Spectroscopy: an Evolution to High-Throughput Techniques BioEnergy Research, 7(1) : 1–23.
Mcdonald, D., Miles, K. and Amiri, R. 2004 The Nature of the Mechanical Pulping Process. Pulp&Paper . Canada.
Mohd Kassim, A.S., Ashuvila M.A., Ishak N., Zainulabidin M.H. 2015. Cogon Grass as an Alternative Fibre for Pulp and Paper-Based Industry: On Chemical and Surface Morphological Properties. In International Integrated Engineering Summit 2014. Trans Tech Publications Ltd (Applied Mechanics and Materials) : 1242–1245.
Oushabi, A., Sair S., Hassani F.O., Abboud Y., Tanane O., Bouri A.L. 2017. The effect of alkali treatment on mechanical, morphological and thermal properties of date palm fibers (DPFs): Study of the interface of DPF–Polyurethane composite. South African Journal of Chemical Engineering, 23 : 116–123.
Popy, R.S., Nayeem J., Arafat K.M.Y., Rahman M.M., Jahan M.S. 2020. Mild potassium hydroxide pulping of straw. Current Research in Green and Sustainable Chemistry 3 : 100015.
Przybysz, P., Dubowik M., Kucner M.A., Przybysz K., Przybysz Buza?a K.. 2016. Contribution of Hydrogen Bonds to Paper Strength Properties’, PloS one, 11(5) : e0155809–e0155809.
Sathawong, S., Sridach, W. and Techato, K. 2018. Lignin: Isolation and preparing the lignin based hydrogel. Journal of Environmental Chemical Engineering, 6(5) : 5879–5888.
Soloi, S. and Hou, E.K.Z. 2019. The Potential of Oil Palm Leaf Fibre in Paper-making Industry.Journal of Physics: Conference Series 1358 : 012005.
Sutradhar, S. Sarkar, A.,Nayeem J., Jahan M., Tian C. 2018. Potassium hydroxide pulping of four non-woods. Bangladesh Journal of Scientific and Industrial Research 53 : 1–6.
Tarasov, D., Leitch, M. and Fatehi, P. 2018. Lignin-carbohydrate complexes: properties, applications, analyses, and methods of extraction: a review. Biotechnology for biofuels 11 : 269–269.
Todorciuc, T. 2009. Characterization of non-wood lignin and its hydoxymethylated derivatives by spectroscopy and self-assembling investigations’, Cellulose Chemistry and Technology 43(9–10) : 399–408.
Tsalagkas, D., Börcsök Z., Pásztory Z., Gogate P., Csoka L. 2021. Assessment of the papermaking potential of processed Miscanthus × giganteus stalks using alkaline pre-treatment and hydrodynamic cavitation for delignification. Ultrasonics sonochemistry 72 : 105462.

Most read articles by the same author(s)